Concrete Additives and Their Types

Concrete Additives and Their Types

Concrete additives are always used in concrete production to improve its mechanical properties and workability. According to the definition in Chapter 9 of the National Building Regulations, an additive is a chemical substance, other than Portland cement, aggregates, and water, that is added in powder or liquid form to modify one or more properties of fresh or hardened concrete. This addition occurs shortly before mixing or during the mixing process.

The amount of concrete additives used is generally small and is not accounted for in the standard mixing ratios. These materials are typically added as a percentage of the cement content in the mix. As specified in Chapter 9 of the National Building Regulations, the maximum amount allowed is 5% of the cement’s weight used in the mixture.

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List of Concrete Additives

Additives are classified as single-purpose if they affect only one property of concrete, or multi-purpose if they influence multiple properties. Based on the type of material, concrete additives are divided into two categories: chemical additives and mineral additives. According to ASTM C-494, additives are classified into eight types:

  • Type A: Water-Reducer (Plasticizer)
  • Type B: Retarder
  • Type C: Accelerator
  • Type D: Water-Reducer and Retarder
  • Type E: Water-Reducer and Accelerator
  • Type F: High-Range Water-Reducer (Superplasticizer)
  • Type G: High-Range Water-Reducer and Retarder
  • Type S: Special Performance Additives

The most commonly used concrete additives include air-entraining agents (foam concrete), water-reducing agents, retarders, and accelerators. Although additives are not considered the primary components of concrete, they are so effective and widespread that producing concrete without additives is considered an exception today.

These additives play a vital role in improving the performance and workability of concrete for different construction projects.

Parsman Chemical – Concrete Additives Manufacturer

Parsman Chemical is a leading manufacturer of concrete additives, utilizing the latest techniques and cutting-edge laboratory equipment from around the world. The company produces a wide range of concrete additives, including superplasticizers, high-range water reducers, normal plasticizers, and products designed to control setting times and foam concrete.

Parsman Chemical is committed to producing specialized products tailored to the specific needs and conditions of various construction projects. The company aims to meet the demands of the construction industry and ensure maximum customer satisfaction.

For consultation and purchasing Parsman Chemical’s products, please contact our experts today.

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Purchase Concrete Additives from Parsman Chemical

To purchase concrete additives from Parsman Chemical, you can take advantage of our wide range of high-quality products. These additives include materials such as polycarboxylate ether, plasticizers, superplasticizers, and other specialized products designed to enhance concrete properties, such as increasing strength, reducing water consumption, and improving workability.

Parsman Chemical utilizes advanced technology and high-quality raw materials to offer the best concrete additive solutions for your construction projects. For consultation and purchasing, please contact our sales team today.

 

To view the products of Parsman Chemical, please visit the Products section.

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Mineral Additives in Concrete

Mineral additives in concrete, in the form of very fine mineral particles, enhance certain properties or impart special characteristics to concrete. These additives can change the color of concrete, improve the workability and cohesiveness of fresh concrete, and increase the strength and impermeability of hardened concrete. Mineral additives in concrete are generally classified into three main categories:

  1. Neutral mineral additives and pigments: Used to change the color or appearance of the concrete.
  2. Pozzolans: Siliceous or siliceous-aluminous materials that act as substitutes or supplements to cement. They do not have cementitious properties on their own, but when finely ground and exposed to moisture, they react chemically with calcium hydroxide to form cement-like compounds.
  3. Cementitious-like additives: Enhance specific cement-like properties.

Pozzolans include siliceous or siliceous-aluminous materials, which by themselves do not have binding value but, when in contact with moisture, react chemically with calcium hydroxide to form cementitious compounds. Pozzolans can partially replace cement in different proportions, leading to reduced cement consumption.

The use of pozzolans in concrete has several benefits, including reducing the rate and amount of heat generated during cement hydration, improving the workability and strength of the concrete, and reducing its permeability. Common pozzolans include natural pozzolans like volcanic ash and industrial pozzolans such as fly ash and silica fume. One of the most widely used pozzolans is microsilica (silica fume), which significantly enhances the strength, durability, and other properties of concrete.

The positive effects of microsilica in concrete are due to two main mechanisms:

  1. High pozzolanic activity: Microsilica reduces calcium hydroxide, a byproduct of cement hydration, while increasing the production of gel, which improves the overall strength of the concrete.
  2. Fineness: Microsilica particles fill the gaps between the cement and gel particles, improving the density and reducing the porosity of the concrete, thereby enhancing its impermeability.

These effects result in stronger, more durable, and less permeable concrete, making microsilica an essential additive in high-performance concrete mixes.

 

Microsilica enhances the adhesion between cement particles and aggregates, thereby reducing the permeability of the concrete. Microsilica particles, which are much finer than cement, fill the pores in the concrete, increasing its strength and reducing permeability.

Neutral mineral additives in concrete do not affect the concrete’s strength but do improve workability and adhesion. These materials typically meet the aggregate requirements for concrete and are used as aggregates in the concrete mix.

Pigments are another type of neutral additive used to change the color of concrete. These color additives come in three forms: powder, granules, or liquid. The powdered form, which has been used the longest, consists of microscopic particles about one-tenth the size of cement particles. These pigment particles are inert, meaning they do not react with the cement but only change the color of the cement during the hydration process.

ASTM C979 is the standard for integrally colored concrete, specifying the amount and type of pigments to be used. The dosage of color additives typically ranges from 1 to 7% of the cement’s weight and should not exceed 10%, as higher amounts can affect the concrete’s strength. Iron oxide is the most commonly used pigment in concrete due to its stability, as it does not fade or wash away over time. The main colors produced by iron oxide pigments are yellow, red, and black, which can be mixed to create a wide range of colors.

Other pigments, such as green (from chromium oxide) and blue (from cobalt), are available but are used less frequently due to their higher cost. Colored concrete has a variety of applications, including decorative structures that require high-end finishes, such as bridges, pavements, and road surfaces, which can help differentiate vehicle lanes or even building facades.

Cementitious-like additives also have latent hydraulic properties. When properly activated, they exhibit cement-like behavior. These additives react similarly to Portland cement only in an alkaline environment with water and, compared to pozzolans, are more similar to ordinary cement. The most common type of this additive is ground granulated blast-furnace slag (GGBFS).

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Chemical Additives for Concrete (Air-Entraining Agents)

The presence of air bubbles in concrete is inevitable, and to some extent, they always form in the mix. Concrete is typically vibrated to minimize these unwanted air bubbles, but they are never completely eliminated.

There are two types of air bubbles in concrete:

  1. Unintentional air bubbles, which are irregular in shape and should be minimized through proper vibration.
  2. Intentional small, spherical air bubbles, which are introduced into the concrete mix through the use of air-entraining additives or air-entraining cement, or a combination of both. These air bubbles improve the performance of concrete in various ways. However, alongside these intentional bubbles, larger, unwanted air bubbles with irregular shapes may also form. Out of the total 4 to 8% air content in the concrete, around 1 to 2% might be these large, unwanted bubbles. Proper vibration can remove some of these unwanted air bubbles, but excessive vibration might also remove the small, intentional air bubbles.

Air-entraining agents are primarily used to enhance the concrete’s resistance to freeze-thaw cycles and to improve its overall workability. Additional benefits of air-entraining agents include:

  • Improved water-tightness.
  • Reduced risk of scaling and flaking.
  • Enhanced resistance to sulfate attacks by providing space for expansion during chemical reactions.
  • Reduced likelihood of aggregate segregation.

On the downside, for every 1% increase in air content, the 28-day compressive strength of the concrete may decrease by 3 to 5%.

Air-entraining additives contain surface-active molecules, which have a hydrophilic (water-attracting) end and a hydrophobic (water-repelling) end. These additives reduce the surface tension of the water in the mix, leading to the formation of small, stable air bubbles. The reduced surface tension prevents these bubbles from coalescing, allowing them to remain stable within the concrete mixture.

 
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Chemical Additives for Concrete (Water-Reducing Agents)

 

According to **ASTM C-494**, chemical additives for concrete that only reduce water content are classified as **Type A**. If they also have retarding properties, they fall under **Type D**, and if they have accelerating properties, they are classified as **Type E**, though these are less commonly used than Type A. Water-reducing agents with stronger effects are classified as **Type F**. One of the primary uses of water-reducing agents is to increase the workability of the concrete mix for better handling, which is why these agents are often referred to as **plasticizers** or **superplasticizers** when they have strong water-reducing properties.

**Plasticizers** and **superplasticizers** serve three main purposes in concrete mixes:
1. To improve workability without changing the water and cement content, making the concrete easier to pour and place.
2. To reduce the water content in the mix, thus lowering the **water-to-cement ratio (W/C)**, leading to higher strength and greater durability at the same workability.
3. To reduce both cement and water consumption at the same workability level, allowing for cost savings in cement usage.

These additives are compatible with various types of cement, and studies show that their effects are even more pronounced in the presence of **pozzolans**. The difference between plasticizers and superplasticizers lies not in their function but in their intensity of action. **Superplasticizers** can reduce water content by 21 to 31% at a constant slump, whereas **plasticizers** typically reduce water by 5 to 12% for the same slump.

Increasing the dosage of plasticizers can enhance water reduction, but it may also negatively affect the concrete’s setting time, air content, and strength. Typically, plasticizers are used at a dosage of 1.2 to 1.4% of the dry cement weight, while superplasticizers are used at around 1.1 to 1.2%. However, these dosages vary depending on the type of chemical additive and the active substance, and are usually specified by the manufacturer.

From a compositional standpoint, plasticizers are quite different from superplasticizers. The main components of superplasticizers are **synthetic water-soluble polymers**, such as:
– **Sulfonated Melamine Formaldehyde** (SMF)
– **Sulfonated Naphthalene Formaldehyde** (SNF)
– **Acrylic Polymers**, such as **Carboxylic Acrylic Acid Copolymers**.

On the other hand, the primary components of plasticizers are **organic compounds**, which can be classified into four groups:
1. The first group includes **lignosulfonate salts**, which can also be modified to function as superplasticizers.
2. The second group includes **hydrocarboxylic acid salts**.
3. The third group includes **carbohydrates**.
4. The fourth group contains miscellaneous compounds such as **glycerol**, **polyvinyl alcohol**, and others.

Figures 1 to 4 illustrate the chemical structures of some common plasticizers.

Parsman Chemical Foam Concrete

In today’s construction industry, lightweighting of both structural and non-structural elements has gained significant importance due to the risks associated with the weight and destruction of heavy elements during earthquakes. As a result, the use of lightweight concrete, mortars, and grouts, particularly in the construction of non-structural elements, is on the rise. Parsman Chemical, leveraging the technical experience and support of its research and development unit, has diversified its product range to include various air-entraining and foaming products aimed at improving the quality and safety of the country’s construction industry.

Foam concrete is a type of lightweight concrete made from cement, sand or fly ash, water, and foam. It is either in the form of foamed grout or foamed mortar. Foam concrete can be defined as a cementitious material with at least 20% foam mechanically added to the plastic mortar. The dry density of foamed concrete can range from 400 to 1600 kg/m³. The compressive strength of foam concrete, measured after 28 days, ranges from 0.2 to 10 N/mm² or higher.

Foam concrete is distinct from air-entrained concrete in terms of the volume of entrained air. While air-entrained concrete contains 3 to 8% air, foam concrete consists of a much higher percentage of air due to the foaming process, which contributes to its lightweight properties.

Foam concrete offers several advantages, including its lightweight nature, ease of production, thermal and acoustic insulation properties, and suitability for a variety of construction applications such as insulating layers, partition walls, and filling voids in non-structural elements.

 
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Advantages of Concrete Additives

Concrete additives, as one of the significant innovations in the construction industry, offer numerous benefits that enhance the quality and performance of concrete. Below are some of the key advantages of using concrete additives:

  1. Increased Concrete Strength
    Additives such as polycarboxylate ether improve the compressive strength of concrete. By reducing the water-to-cement ratio while maintaining the mix’s workability, the final strength of the concrete is increased, resulting in more durable structures.

  2. Improved Workability and Flowability
    The use of plasticizers and superplasticizers makes the concrete easier to work with and pump. This is especially important in large and complex projects where high workability is essential.

  3. Reduced Water Consumption
    One of the most important advantages of concrete additives is reducing the water required in the mix. This reduction not only saves resources but also increases the density and quality of the concrete.

  4. Reduced Shrinkage and Cracking
    Some additives help reduce concrete shrinkage and prevent cracking during drying. This leads to increased durability and longevity of concrete in various weather conditions.

  5. Increased Durability and Resistance to Environmental Conditions
    Specific additives make concrete more resistant to environmental factors such as moisture, freeze-thaw cycles, chemicals, and corrosive conditions. This is particularly crucial for projects exposed to harsh environments.

  6. Time and Cost Savings
    By improving the properties of concrete and reducing curing time, construction projects can save time and reduce overall construction costs.

  7. Extended Lifespan of Structures
    Additives improve the mechanical properties and durability of concrete, thus extending the lifespan of structures and reducing the need for repairs and maintenance over time.

These benefits make concrete additives essential for modern construction, contributing to more efficient, durable, and cost-effective projects.

Disadvantages of Concrete Additives

While concrete additives offer numerous benefits in improving the performance and efficiency of concrete, like any product, they may present certain challenges in specific conditions. For example, improper or excessive use of these materials can alter the setting time of the concrete or lead to issues like incompatibility with other materials. However, Parsman Chemical minimizes these concerns by providing high-quality additives and leveraging its team of specialists. With proper guidance and precise usage, our products can be used in your projects without any issues. Selecting the right additives and carefully controlling the dosage is key to achieving optimal results.

While some may point out the potential drawbacks of concrete additives, Parsman Chemical addresses all related concerns by offering advanced and optimized concrete additives. Our products are developed using the latest technologies to deliver the best performance without negative impacts on setting time or compatibility with other materials. Moreover, our expert team provides precise solutions and specialized consultations to assist you in using additives correctly and managing dosage with accuracy. With Parsman Chemical products, you can be confident that all your project needs will be met with the highest quality and efficiency.

Conclusion

Using concrete additives in construction projects not only improves the quality and performance of concrete but also helps save costs, increase structural durability, and enhance resistance to environmental conditions. Parsman Chemical offers a wide range of high-quality additives, making us your reliable partner in achieving excellent results in your construction projects. For consultation and purchasing, contact us today to benefit from our expertise and experience.